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TECHNICAL DESCRIPTION
The aim of this
invention is to provide a complex able to form an adduit with a salt, the
aforementioned adduit having a nucleophilic anion part and being soluble in
polar solvents aprotic.
The invention
rests primarily on the fact that, in an unexpected way, complexes formed by an acid of Lewis derived from boron or
aluminum are able to form complexes with an anion Z chosen among F ('), OCN
('), O (2 '), O [2] (2 '), O [2] (' '), OH ('), RO ('), RN (2') 'R [2] NR (')
and CN ('), HNCN ('1) NCN (2') and NR (3') of a salt whose cation can be an
alkaline cation.
It relates to
boron or aluminum complexes, to the preparation thereof, and to the use thereof
for solubilizing ion components. The
complexes have one of the following formulas: (I, II, III, IV, V, and VI)
wherein D is B or Al; R1 is R, RF, NO2, CN, C(=O)OR, RSO2, or RFSO2; X1, X2,
X3, and X4 each is a divalent group >C=O, >C=NC N, >C=C(C N)2,
>CR2R3, or >SO2; Y1, Y2, and Y3, each is a divalent group -O-, >N(C
N), >N(CORF), >N(SO2R4), >NR4, >N(COR4), or >N(SO2RF); R1, R2,
and R3, each is H, an alkyl group, an aryl group, an alkylaryl group, an
arylalkyl group, an oxaalkyl group, or an alkenyl group; R4 is an alkyl group,
an aryl group, an alkylaryl group, a heteroaryl group, an arylalkyl group, an
oxaalkyl group, an alkenyl group, or an RFCH2 group; RF is a perfluoroalkyl
group, partially fluoridated alkyl group, or a partially or totally fluoridated
phenyl group; each of groups R'2 and R'3 is R or F.
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